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μ2-Oxo-bis­[bis(η5-1,3-di-tert-butylcyclo­penta­dienyl)­titanium(III)]

✍ Scribed by Sofield, Chadwick D. ;Walter, Marc D. ;Andersen, Richard A.

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
241 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Ti 2 O(C 13 H 21 ) 4 ] or {[(1,3-t Bu 2 -C 5 H 3 ) 2 Ti} 2 (" 2 -O)}, crystallizes as a centrosymmetric molecule, in which the two metallocene fragments are bridged by an O atom. The trigonal planar coordination around each metal consists of two 1,3-t Bu 2 C 5 H 3 ligands and the bridging O atom. The O atom is located on a crystallographic inversion center, resulting in a linear TiÐOÐTi linkage.

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