trans-Di-μ-chloro-bis[chloro(triphenylphosphine)palladium] benzene disolvate
✍ Scribed by Sui-Seng, Christine ;Bélanger-Gariépy, Francine ;Zargarian, Davit
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 197 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 220 K Mean '(C±C) = 0.005 A Ê R factor = 0.034 wR factor = 0.089 Data-to-parameter ratio = 17.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The title compound, [Pd 2 Cl 2 ("-C 6 H 5 Se) 2 (C 18 H 15 P) 2 ], crystallizes as a centrosymmetric phenylselenolato-bridged dinuclear palladium complex. The Pd atom shows a slightly distorted square-planar coordination geometry, with the PdÐSe distance trans to the terminal Cl À ligand at 2.4174 (
In the centrosymmetric dinuclear title complex, [RuCl 2 ( 6 -C 6 H 6 )] 2 Á2CHCl 3 or [Ru 2 Cl 4 (C 6 H 6 ) 2 ]Á2CHCl 3 , accessible from RuCl 3 .nH 2 O and 1,3-cyclohexadiene, the benzene ligands are involved in slipped-parallelstacking interactions with neighbouring molecules, thus forming one-dim