In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si
Chlorobis(2-chlorobenzyl)(4-ethylpiperazine-1-dithiocarbamato-κ2S,S′)tin(IV)
✍ Scribed by Li, Jun-Ying ;Li, Tian-Duo
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 111 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Sn(C~7~H~6~Cl)~2~(C~7~H~13~N~2~S~2~)Cl], the Sn atom is five-coordinate in a trigonal–bipyramidal geometry. One Sn—S bond is markedly longer than the other for the chelating dithiocarbamate ligand.
📜 SIMILAR VOLUMES
In the crystal structure of the title complex, [Cu^II^(C~3~H~6~NS~2~)Cl(C~12~H~8~N~2~)], the Cu^II^ atom has a distorted square-pyramidal coordination geometry comprising one __S__,__S__′-bidentate dimethyldithiocarbamate (Me~2~dtc) ligand, one __N__,__N__′-bidentate 1,10-phenanthroline (phen) ligan
In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed betwee