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Chloro­(N,N′-dimethyl­dithio­carbamato-κ2S,S′)(1,10-phenanthroline-κ2N,N′)copper(II)

✍ Scribed by Nobuo, Okabe ;Munehiro, Tomoda ;Mamiko, Odoko ;Masahiro, Yodoshi

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
220 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the crystal structure of the title complex, [Cu^II^(C~3~H~6~NS~2~)Cl(C~12~H~8~N~2~)], the Cu^II^ atom has a distorted square-pyramidal coordination geometry comprising one S,S′-bidentate dimethyldithiocarbamate (Me~2~dtc) ligand, one N,N′-bidentate 1,10-phenanthroline (phen) ligand and an apical Cl atom. A mirror plane passes through the Cu and Cl atoms, and also through the C__sp__
^2^—N bond of the dithiocarbamate. The complex molecules are linked together by C—H...Cl hydrogen bonds, forming a bilayered one-dimensional chain along the a axis.

📜 SIMILAR VOLUMES

(Dimethyldithiocarbamato-κ2S,S′)iodido(1
(Dimethyldithiocarbamato-κ2S,S′)iodido(1,10-phenanthroline-κ2N,N′)copper(II)
✍ Fan, Le-Qing ;Wu, Ji-Huai 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 720 KB

In the title complex, [Cu(C 3 H 6 NS 2 )I(C 12 H 8 N 2 )], each Cu II atom is coordinated by one iodide ion, two N atoms from a phenanthroline ligand and two S atoms from a dimethyldithiocarbamate ligand in a distorted square-pyramidal environment. There are two molecules in the asymmetric unit.

(2,2′-Bipyridine-κ2N,N′)(N,N-diethyl­dit
(2,2′-Bipyridine-κ2N,N′)(N,N-diethyl­dithio­carbamato-κ2S,S′)iodocopper(II)
✍ Fan, Le-Qing ;Wu, Ji-Huai 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 112 KB

In the title compound, [Cu(C 5 H 10 NS 2 )I(C 10 H 8 N 2 )], the Cu II ion is coordinated by one iodide ion, two N atoms of the bipyridine ligand and two S atoms from the diethyldithiocarbamate ligand in a distorted square pyramidal geometry. metal-organic papers m2892 Fan and Wu [Cu(C 5 H 10 NS 2 )

Di-tert-butyl­chloro­(N,N-dimethyl­dithi
Di-tert-butyl­chloro­(N,N-dimethyl­dithio­carbamato-κ2S,S′)tin(IV)
✍ Li, Feng ;Yin, Han-Dong ;Zhai, Jun ;Wang, Da-Qi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 108 KB

In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si