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(Dimethyldithiocarbamato-κ2S,S′)iodido(1,10-phenanthroline-κ2N,N′)copper(II)

✍ Scribed by Fan, Le-Qing ;Wu, Ji-Huai


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
720 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the title complex, [Cu(C 3 H 6 NS 2 )I(C 12 H 8 N 2 )], each Cu II atom is coordinated by one iodide ion, two N atoms from a phenanthroline ligand and two S atoms from a dimethyldithiocarbamate ligand in a distorted square-pyramidal environment. There are two molecules in the asymmetric unit.


📜 SIMILAR VOLUMES


Chloro­(N,N′-dimethyl­dithio­carbamato-κ
✍ Nobuo, Okabe ;Munehiro, Tomoda ;Mamiko, Odoko ;Masahiro, Yodoshi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 220 KB

In the crystal structure of the title complex, [Cu^II^(C~3~H~6~NS~2~)Cl(C~12~H~8~N~2~)], the Cu^II^ atom has a distorted square-pyramidal coordination geometry comprising one __S__,__S__′-bidentate dimethyldithiocarbamate (Me~2~dtc) ligand, one __N__,__N__′-bidentate 1,10-phenanthroline (phen) ligan

[1-(Diphenylphosphino)-2-(diphenylphosph
✍ Zhang, Xiao-Lin ;Wu, Wen-Hong ;Cao, Qian-Yong ;Li, Yong-Xiu ;Luo, Lai-Tao 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 165 KB

In the structure of the title complex, [CuI(C 12 H 8 N 2 )-{Ph 2 PCH 2 CH 2 P(O)Ph 2 }]ÁCH 2 Cl 2 , the coordination polyhedron with copper as the central atom has a distorted tetrahedral geometry formed by two N atoms from 1,10phenanthroline, one iodide anion and one P atom from 1-(diphenylphosphin

Bis(glycolato-κ2O,O′)(1,10-phenanthrolin
✍ Du, Lin ;Zhang, Yu-Hua ;Fang, Rui-Bing ;Zhao, Qi-Hua 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 236 KB

The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h