(Dimethyldithiocarbamato-κ2S,S′)iodido(1,10-phenanthroline-κ2N,N′)copper(II)
✍ Scribed by Fan, Le-Qing ;Wu, Ji-Huai
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 720 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title complex, [Cu(C 3 H 6 NS 2 )I(C 12 H 8 N 2 )], each Cu II atom is coordinated by one iodide ion, two N atoms from a phenanthroline ligand and two S atoms from a dimethyldithiocarbamate ligand in a distorted square-pyramidal environment. There are two molecules in the asymmetric unit.
📜 SIMILAR VOLUMES
In the crystal structure of the title complex, [Cu^II^(C~3~H~6~NS~2~)Cl(C~12~H~8~N~2~)], the Cu^II^ atom has a distorted square-pyramidal coordination geometry comprising one __S__,__S__′-bidentate dimethyldithiocarbamate (Me~2~dtc) ligand, one __N__,__N__′-bidentate 1,10-phenanthroline (phen) ligan
In the structure of the title complex, [CuI(C 12 H 8 N 2 )-{Ph 2 PCH 2 CH 2 P(O)Ph 2 }]ÁCH 2 Cl 2 , the coordination polyhedron with copper as the central atom has a distorted tetrahedral geometry formed by two N atoms from 1,10phenanthroline, one iodide anion and one P atom from 1-(diphenylphosphin
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h