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[1-(Diphenylphosphino)-2-(diphenylphosphinoyl)ethane-κP1]iodido(1,10-phenanthroline-κ2N,N′)copper(I) dichloromethane solvate

✍ Scribed by Zhang, Xiao-Lin ;Wu, Wen-Hong ;Cao, Qian-Yong ;Li, Yong-Xiu ;Luo, Lai-Tao

Publisher: International Union of Crystallography
Year: 2007
Tongue: English
Weight: 165 KB
Volume: 63
Category: Article
ISSN: 1600-5368
DOI: 10.1107/s1600536807010392

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✦ Synopsis

In the structure of the title complex, [CuI(C 12 H 8 N 2 )-{Ph 2 PCH 2 CH 2 P(O)Ph 2 }]ÁCH 2 Cl 2 , the coordination polyhedron with copper as the central atom has a distorted tetrahedral geometry formed by two N atoms from 1,10phenanthroline, one iodide anion and one P atom from 1-(diphenylphosphino)-2-(diphenylphosphinoyl)ethane.

📜 SIMILAR VOLUMES

Chloro[1-(diphenylphosphinoyl)-2-(dip

Chloro[1-(diphenylphosphinoyl)-2-(diphenylphosphino)ethane-κP2](1,10-phenanthroline-κ2N,N′)copper(I) dichloromethane solvate

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In the title complex, [Cu(C 3 H 6 NS 2 )I(C 12 H 8 N 2 )], each Cu II atom is coordinated by one iodide ion, two N atoms from a phenanthroline ligand and two S atoms from a dimethyldithiocarbamate ligand in a distorted square-pyramidal environment. There are two molecules in the asymmetric unit.

(1-Formyl-2-naphtholato-κ2O,O′)dioxo(1,1

(1-Formyl-2-naphtholato-κ2O,O′)dioxo(1,10-phenanthroline-κ2N,N′)vanadium(V) dichloromethane 0.25-solvate

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catena-Poly[[[aqua(1,10-phenanthroline-κ

catena-Poly[[[aqua(1,10-phenanthroline-κ2N,N′)sodium(I)]-μ-aqua-[diaqua(1,10-phenanthroline-κ2N,N′)sodium(I)]-μ-aqua] dibromide 1,10-phenanthroline solvate]

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catena-Poly[ [[aqua(1,10-phenanthrolinej 2 N,N 0 0 0 )sodium(I)]-l-aqua-[diaqua(1,10phenanthroline-j 2 N,N 0 0 0 )sodium(I)]-laqua] dibromide 1,10-phenanthroline solvate]

Di-μ-iodo-bis[(1,10-phenanthroline-κ2N,

Di-μ-iodo-bis[(1,10-phenanthroline-κ2N,N′)copper(I)] acetonitrile solvate

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In the title complex, [Cu 2 I 2 (C 12 H 8 N 2 ) 2 ]ÁC 2 H 3 N, two Cu I atoms are bridged by two I atoms and each Cu I atom is chelated by a 1,10-phenanthroline ligand to give four-coordinate tetrahedral geometry.