Dichloro(N,N′-diethyldithiocarbamato-κ2S,S′)(4-methylpentan-2-onato-κ2C4,O)tin(IV)
✍ Scribed by Tiekink, Edward R. T. ;Wardell, James L. ;Welte, William B.
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 350 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The Sn atom in the title compound, [SnBr(C~6~H~5~)~2~(C~3~H~6~NS~2~)], adopts a distorted SnBrC~2~S~2~ trigonal–bipyramidal environment.
In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si
In the title complex, [Sn(C~7~H~6~Cl)~2~(C~7~H~13~N~2~S~2~)Cl], the Sn atom is five-coordinate in a trigonal–bipyramidal geometry. One Sn—S bond is markedly longer than the other for the chelating dithiocarbamate ligand.
In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in
A seven-coordinated tin(IV) complex: dichloro[2,6-diacetylpyridine bis(S-benzyldithiocarbazato-j 5 S,N,N 0 0 0 ,N 0 0 00 0 0 ,S 0 0 0 ]tin(IV) Gerima ´rio F. de Sousa, a \* Jesu ´s Valde ´s Martı ´nez b and Simo ´n Herna ´ndez-Ortega b a