Bromo(N,N-dimethyldithiocarbamato-κ2S,S′)diphenyltin(IV)
✍ Scribed by Tian, Lai-Jin ;Mao, Wu-Tao ;Sun, Yu-Xi ;Liu, Xi-Cheng
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 126 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The Sn atom in the title compound, [SnBr(C~6~H~5~)~2~(C~3~H~6~NS~2~)], adopts a distorted SnBrC~2~S~2~ trigonal–bipyramidal environment.
📜 SIMILAR VOLUMES
In the title compound, [Sn(C 4 H 9 ) 2 (C 3 H 6 NS 2 )Cl], the Sn IV atom has a distorted trigonal bipyramidal geometry that is defined by Cl, two S and two C atoms. The dithiocarbamate chelates to the Sn atom in an anisobidentate manner, and the double-bonded S atom occupies one of the two axial si
In the crystal structure of the title complex, [Cu^II^(C~3~H~6~NS~2~)Cl(C~12~H~8~N~2~)], the Cu^II^ atom has a distorted square-pyramidal coordination geometry comprising one __S__,__S__′-bidentate dimethyldithiocarbamate (Me~2~dtc) ligand, one __N__,__N__′-bidentate 1,10-phenanthroline (phen) ligan