The molecule of the title compound, [Sn(C 2 H 5 ) 2 (C 11 H 12 N 3 -O 2 S 2 )Cl], features an asymmetrically chelating thiocarboxylate ligand. The Sn atom is five-coordinate within a C 2 ClS 2 donor set that is best described as trigonal bipyramidal with S and Cl atoms in axial positions, defining a
Dibutylchloro[4-(4-nitrophenyl)piperazine-1-carbodithioato-κ2S,S′]tin(IV)
✍ Scribed by Zia-ur-Rahman, ;Ali, Saqib ;Muhammed, Niaz ;Meetsma, Auke
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 144 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, [Sn(C~7~H~6~Cl)~2~(C~7~H~13~N~2~S~2~)Cl], the Sn atom is five-coordinate in a trigonal–bipyramidal geometry. One Sn—S bond is markedly longer than the other for the chelating dithiocarbamate ligand.
In the zigzag polymeric title compound, [Sn(CH 3 ) 3 -(C 16 H 20 NO 3 )] n , the Sn atom adopts a distorted trigonalbipyramidal geometry.
In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed betwee