Bis[1-(4-nitrobenzyl)pyridinium] bis(2,2-dicyanoethylene-1,1-dithiolato-κ2S,S′)nickelate(II)
✍ Scribed by Liu, Ming-Guo ;Li, Xiao-Yan ;Lin, Li-Fa ;Ni, Chun-Lin
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 147 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed between anions and cations in the crystal structure.
📜 SIMILAR VOLUMES
A new ion-pair complex, (C 14 anion, which is located on an inversion center, exhibits a planar structure. The crystal packing is governed by short C-HÁ Á ÁN and C-HÁ Á ÁS contacts between anions and cations and bystacking interactions between the phenyl groups of the cations (the centroid-centroid