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Bis[1-(4-nitro­benz­yl)pyridinium] bis­(2,2-dicyano­ethyl­ene-1,1-dithiol­ato-κ2S,S′)nickelate(II)

✍ Scribed by Liu, Ming-Guo ;Li, Xiao-Yan ;Lin, Li-Fa ;Ni, Chun-Lin


Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
147 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis


In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed between anions and cations in the crystal structure.


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Bis[1-benzyl-4-(dimethylamino)pyridinium
✍ Feng, Chu-Wen ;Li, Xiang-Rong ;Hou, Yong ;Ni, Chun-Lin 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 857 KB

A new ion-pair complex, (C 14 anion, which is located on an inversion center, exhibits a planar structure. The crystal packing is governed by short C-HÁ Á ÁN and C-HÁ Á ÁS contacts between anions and cations and bystacking interactions between the phenyl groups of the cations (the centroid-centroid