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Bis[4-methyl-1-(4-nitro­benz­yl)pyridinium] bis­(1,2,5-thia­diazole-3,4-dithiol­ato)nickelate(II)

✍ Scribed by Liu, Ming-Guo ;Ni, Chun-Lin

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
181 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed betwee

Bis(N-methyl­pyridinium) bis­(2-thioxo-1
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In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.