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Bis(N-methyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)

✍ Scribed by Wang, Yan-Ling ;Yu, Wen-Tao ;Xu, Dong ;Wang, Xin-Qiang ;Guo, Wen-Feng ;Zhang, Guang-Hui

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
310 KB
Volume
61
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.

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In the title compound, (C 4 H 12 N) 2 [Cu(C 3 S 5 ) 2 ], the Cu II atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry.

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Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.005 A Ê R factor = 0.051 wR factor = 0.168 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.