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N-Benzyl­pyridinium bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)nickel(III)

✍ Scribed by Yang, Guo-Zhong ;Yao, Li ;Cui, Xue-Yu

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
160 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title ion-pair compound, (C 12 H 12 N)[Ni(C 3 S 5 ) 2 ], the Ni III atom exhibits a square-planar coordination geometry with four S atoms of the two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands. Some weak SÁ Á ÁS interactions are found.

📜 SIMILAR VOLUMES

Bis(N-methyl­pyridinium) bis­(2-thioxo-1
Bis(N-methyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)
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In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.

Bis(N-ethyl­pyridinium) bis­(2-thioxo-1,
Bis(N-ethyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)
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In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy

Bis(N-methyl­pyridinium) bis­(2-thioxo-1
Bis(N-methyl­pyridinium) bis­(2-thioxo-1,3-dithione-4,5-dithiol­ato)cadmate(II)
✍ Wang, Yan-Ling ;Wang, Yong-Jin ;Wang, Rui-He ;Yao, Jun ;Zhao, Xiu-Tai 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 86 KB

In the title complex, (C 6 H 8 N) 2 [Cd(C 3 S 5 ) 2 ], the Cd II ion is coordinated by four dmit (2-thioxo-1,3-dithione-4,5-dithiolate) S atoms in a distorted tetrahedral geometry. The Nmethylpyridinium cations link with the Cd II complex anion via weak C-HÁ Á ÁS hydrogen bonding.