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Bis(N-ethyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)

✍ Scribed by Wang, Yan-Ling ;Yu, Wen-Tao ;Chen, Hong-Yu ;Xu, Dong ;Guo, Wen-Feng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
139 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror symmetry.

📜 SIMILAR VOLUMES

Bis(N-methyl­pyridinium) bis­(2-thioxo-1
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In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.

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In the title ion-pair compound, (C 12 H 12 N)[Ni(C 3 S 5 ) 2 ], the Ni III atom exhibits a square-planar coordination geometry with four S atoms of the two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands. Some weak SÁ Á ÁS interactions are found.

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In the title complex, (C 6 H 8 N) 2 [Cd(C 3 S 5 ) 2 ], the Cd II ion is coordinated by four dmit (2-thioxo-1,3-dithione-4,5-dithiolate) S atoms in a distorted tetrahedral geometry. The Nmethylpyridinium cations link with the Cd II complex anion via weak C-HÁ Á ÁS hydrogen bonding.

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In the title compound, (C 4 H 12 N) 2 [Cu(C 3 S 5 ) 2 ], the Cu II atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry.

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Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.005 A Ê R factor = 0.051 wR factor = 0.168 Data-to-parameter ratio = 18.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.