Bis(tetraphenylphosphonium) bis(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II)
✍ Scribed by Candiota, Rafael O. ;Comerlato, Nadia M. ;Howie, R. Alan ;Wardell, James L.
- Publisher
- International Union of Crystallography
- Year
- 2003
- Tongue
- English
- Weight
- 274 KB
- Volume
- 59
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
Single-crystal X-ray study T = 120 K Mean '(C±C) = 0.005 A Ê R factor = 0.051 wR factor = 0.168 Data-to-parameter ratio = 18.9
For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
📜 SIMILAR VOLUMES
The title compounds were prepared from 1,3,4,6tetrathiapentalene-2,5-dione (1) in one step via the in situ The X-ray single crystal structure of (Et 4 N) 2 [Zn(dmid) 2 ] (3 a) gave the tetragonal space group P4 3 2 1 2 with a = b = 13.810(2) A Ê , c = 16.480(3) A Ê , and Z = 4. (n-Bu 4 N) 2 [Zn(dmi
In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.
In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.007 A Ê R factor = 0.038 wR factor = 0.095 Data-to-parameter ratio = 19.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.