In the title compound, (C 4 H 12 N) 2 [Cu(C 3 S 5 ) 2 ], the Cu II atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry.
Bis(tetraphenylphosphonium) bis(2-thioxo-1,3-dithiole-4,5-dithiolato)cuprate(II)
✍ Scribed by Wang, Rui-He ;Wang, Yan-Ling ;Yao, Jun ;Zhao, Xiu-Tai
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 133 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.
In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy