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Bis(tetra­methyl­ammonium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)cuprate(II)

✍ Scribed by Wang, Yan-Ling ;Yu, Wen-Tao ;Xu, Dong

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
132 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title compound, (C 4 H 12 N) 2 [Cu(C 3 S 5 ) 2 ], the Cu II atom lies on a centre of inversion and is coordinated by four S atoms from two 2-thioxo-1,3-dithiole-4,5-dithiolate ligands in a square-planar geometry.

📜 SIMILAR VOLUMES

Bis(N-methyl­pyridinium) bis­(2-thioxo-1
Bis(N-methyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)
✍ Wang, Yan-Ling ;Yu, Wen-Tao ;Xu, Dong ;Wang, Xin-Qiang ;Guo, Wen-Feng ;Zhang, Gu 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 310 KB

In the title complex, (C 6 H 8 N) 2 [Zn(dmit) 2 ] (dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, C 3 S 5 ), each Zn atom is coordinated by four dmit S atoms that define a distorted tetrahedral arrangement. The crystal structure is stabilized by C-HÁ Á ÁS hydrogen bonding and SÁ Á ÁS contacts.

Bis(N-ethyl­pyridinium) bis­(2-thioxo-1,
Bis(N-ethyl­pyridinium) bis­(2-thioxo-1,3-dithiole-4,5-dithiol­ato)zincate(II)
✍ Wang, Yan-Ling ;Yu, Wen-Tao ;Chen, Hong-Yu ;Xu, Dong ;Guo, Wen-Feng 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 139 KB

In the title compound, (C 7 H 10 N) 2 [Zn(C 3 S 5 ) 2 ], the Zn II ion is located on a twofold axis and coordinated by four 2-thioxo-1,3-dithiole-4,5-dithiolate S atoms with a distorted tetrahedral geometry. The asymmetric unit contains two independent Nethylpyridinium cations, each having mirror sy