Synthesis and Crystal Structures of Bis(tetraethylammonium)(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II) and Bis(tetra-n-butylammonium)(2-oxo-1,3-dithiole-4,5-dithiolato)zincate(II)

✍ Scribed by Harald Müller; Anna Puig Molina; B. Zh. Narymbetov; L. V. Zorina; S. S. Khasanov; R. P. Shibaeva

• Publisher: John Wiley and Sons
• Year: 1998
• Tongue: German
• Weight: 112 KB
• Volume: 624
• Category: Article
• ISSN: 0372-7874
• DOI: 10.1002/(sici)1521-3749(199809)624:9<1492::aid-zaac1492>3.0.co;2-7

✦ Synopsis

The title compounds were prepared from 1,3,4,6tetrathiapentalene-2,5-dione (1) in one step via the in situ

The X-ray single crystal structure of (Et 4 N) 2 [Zn(dmid) 2 ] (3 a) gave the tetragonal space group P4 3 2 1 2 with a = b = 13.810(2) A Ê , c = 16.480(3) A Ê , and Z = 4. (n-Bu 4 N) 2 [Zn(dmid) 2 ] (3 b) gave the triclinic space group P 1 with a = 11.947(4) A Ê , b = 14.665(5) A Ê , c = 16.662(8) A Ê , α = 100.21(3)°, b = 104.46(3)°, c = 110.73(3)°, and Z = 2.