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Bis[(4-bromo­benz­yl)triphenyl­phosphonium] bis­(1,2-dicyano­ethane-1,2-dithiol­ato-κ2S,S′)nickel(II) monohydrate

✍ Scribed by Yang, Shui-Bin ;Ni, Chun-Lin

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
194 KB
Volume
62
Category
Article
ISSN
1600-5368

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In the new ion-pair title complex, (C 12 2À , where NO 2 BzPy + is 1-(4-nitrobenzyl)pyridinium and i-mnt is 2,2-dicyanoethylene-1,1-dithiolate, the [Ni(i-mnt) 2 ] 2À complex anion lies on an inversion centre and exhibits an almost structure. Weak C-HÁ Á ÁN and C-HÁ Á ÁNi contacts are observed betwee

Bis[(3-fluorobenzyl)triphenylphosphonium
Bis[(3-fluorobenzyl)triphenylphosphonium] bis(1,2-dicyanoethene-1,2-dithiolato-κ2S,S′)nickel(II)
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In the title salt, (C~25~H~21~FP)~2~[Ni(C~4~N~2~S~2~)~2~], the Ni^II^ ion lies on an inversion centre and the [Ni(mnt)~2~]^2−^ anion (mnt is maleonitriledithiolate) exhibits a square-planar coordination geometry. The (3-fluorobenzyl)triphenylphosphonium cation adopts a conformation in which the four