Chlorodiethyl[4-(4-nitrophenyl)piperazine-1-carbodithioato]tin(IV)
✍ Scribed by Zia-ur-Rahman, ;Ali, Saqib ;Muhammad, Niaz ;Meetsma, Auke
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 103 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The molecule of the title compound, [Sn(C 2 H 5 ) 2 (C 11 H 12 N 3 -O 2 S 2 )Cl], features an asymmetrically chelating thiocarboxylate ligand. The Sn atom is five-coordinate within a C 2 ClS 2 donor set that is best described as trigonal bipyramidal with S and Cl atoms in axial positions, defining a bond angle of 156.58 (2) .
📜 SIMILAR VOLUMES
In the title __N__,__S__-substituted compound, C~20~H~16~Cl~4~FN~3~O~2~S, the piperazine ring adopts a chair conformation. The butadiene unit assumes a configuration close to __cisoid__.
The title compound, C 23 H 26 ClN 5 O 2 , was synthesized by the reaction of 4- [(2,6-dimethylphenyl)aminocarbonylmethyl]piperazine and 5-chloromethyl-3-(2-chlorophenyl)-1,2,4oxadiazole. In the structure, there are intramolecular C-HÁ Á ÁN, N-HÁ Á ÁN and C-HÁ Á ÁO hydrogen bonds, and intermolecular
Acta Cryst. (2006). E62, m451-m453 Aziz-ur-Rehman et al. [Sn(CH 3 ) 3 (C 15 H 15 O 2 )] m453