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catena-Poly[[bis­(O,O′-diisopropyl dithio­phosphato-κ2S,S′)zinc(II)]-μ-1,2-bis­(3-pyridylmethyl­ene)hydrazine-κ2N:N′]

✍ Scribed by Avila, Vanessa ;Tiekink, Edward R. T.

Book ID
111709902
Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
186 KB
Volume
62
Category
Article
ISSN
1600-5368

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catena-Poly[[bis­(O,O′-diisopropyl dithi
catena-Poly[[bis­(O,O′-diisopropyl dithiophosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethyl­ene-κ2N:N′]
✍ Welte, William B. ;Tiekink, Edward R. T. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 341 KB

In the zigzag polymeric title compound, [Zn{S~2~P(O^i^Pr)~2~}~2~{NC~5~H~4~C(H)=C(H)C~5~H~4~N}]~__n__~ or [Zn(C~6~H~14~O~2~PS~2~)~2~(C~12~H~10~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry.

catena-Poly[[bis­(O,O′-diethyl dithio­ph
catena-Poly[[bis­(O,O′-diethyl dithio­phosphato-κ2S,S′)zinc(II)]-μ-1,2-di-4-pyridylethane-κ2N:N′]
✍ Tiekink, Edward R. T. ;Wardell, James L. ;Welte, William B. 📂 Article 📅 2007 🏛 International Union of Crystallography 🌐 English ⚖ 256 KB

In the zigzag polymeric title compound, [Zn(S~2~P(OEt)~2~)~2~(NC~5~H~4~CH)~2~CH~2~C~5~H~4~N)]~__n__~ or [Zn(C~4~H~10~O~2~PS~2~)~2~(C~12~H~12~N~2~)]~__n__~, the Zn atom adopts a distorted tetrahedral ZnN~2~S~2~ geometry; the bridging di-4-pyridylethane molecules are each disposed about a centre of in