In the title mononuclear cobalt(III) complex, [Co(C 11 H 14 -N 3 O 3 ) 2 ]NO 3 , the octahedral Co III atom is coordinated by two phenolate O atoms, two imine N atoms, and two amine N atoms from two Schiff base ligands. The Co III complex and the nitrate anion possess crystallographic twofold rotati
Bis{2-[2-(hydroxymethyl)phenyliminomethyl]phenolato}cobalt(III) nitrate monohydrate
✍ Scribed by Muto, Masahiro ;Nakagawa, Natsumi ;Koikawa, Masayuki ;Tokii, Tadashi
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 236 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-organic papers m66 Muto et al. [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O Acta Cryst. (2007). E63, m64-m66
📜 SIMILAR VOLUMES
The title compound, [Zn(C 15 H 14 NO 2 ) 2 ]ÁH 2 O, is a mononuclear zinc(II) compound. The Zn II atom, located on an inversion centre, is coordinated by two N atoms and two O atoms from two Schiff base ligands in a square-planar geometry. The O-HÁ Á ÁO hydrogen bonding involving the water molecules
In the title compound, [Cu(C 11 H 14 NO 4 )Cl], the tridentate Schiff base ligand coordinates to the metal atom through the N and O atoms, forming a square-planar coordination geometry.
In the cation of the title complex, [Zn(C 13 H 10 BrN 2 O)(H 2 O)]-(NO 3 )ÁH 2 O, the Zn atom is coordinated by two N and two O atoms, giving a slightly distorted square-planar geometry. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.