Bis{2,4-dichloro-6-[2-(isopropylamino)ethyliminomethyl]phenolato}cobalt(III) perchlorate monohydrate
✍ Scribed by Zhao, Xiao-Fan
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 326 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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In the title mononuclear cobalt(III) complex, [Co(C 11 H 14 -N 3 O 3 ) 2 ]NO 3 , the octahedral Co III atom is coordinated by two phenolate O atoms, two imine N atoms, and two amine N atoms from two Schiff base ligands. The Co III complex and the nitrate anion possess crystallographic twofold rotati
Single-crystal X-ray study T = 298 K Mean (C-C) = 0.005 A R factor = 0.044 wR factor = 0.100 Data-to-parameter ratio = 21.3 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-