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Bis{2-[2-(ethyl­amino)ethyl­imino­meth­yl]-4-nitro­phenolato}cobalt(III) nitrate

✍ Scribed by Lin, Hong-Wei ;Chen, Zhen-Feng

Publisher
International Union of Crystallography
Year
2006
Tongue
English
Weight
286 KB
Volume
62
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title mononuclear cobalt(III) complex, [Co(C 11 H 14 -N 3 O 3 ) 2 ]NO 3 , the octahedral Co III atom is coordinated by two phenolate O atoms, two imine N atoms, and two amine N atoms from two Schiff base ligands. The Co III complex and the nitrate anion possess crystallographic twofold rotation axis symmetry. The nitrate anions are linked to the cobalt(III) complexes through intermolecular N-HÁ Á ÁO hydrogen bonds.

📜 SIMILAR VOLUMES

Bis{2-[2-(hydroxy­meth­yl)­phenyl­imino­
Bis{2-[2-(hydroxy­meth­yl)­phenyl­imino­meth­yl]­phenolato}cobalt(III) nitrate monohydrate
✍ Muto, Masahiro ;Nakagawa, Natsumi ;Koikawa, Masayuki ;Tokii, Tadashi 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 236 KB

The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-