The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-
trans-Bis{2-[(4-hydroxyphenethylimino)methyl]phenolato}zinc(II) monohydrate
✍ Scribed by Xu, Hua-Jie ;Liu, Zhao-Di ;Sheng, Liang-Quan
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 292 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The title compound, [Zn(C 15 H 14 NO 2 ) 2 ]ÁH 2 O, is a mononuclear zinc(II) compound. The Zn II atom, located on an inversion centre, is coordinated by two N atoms and two O atoms from two Schiff base ligands in a square-planar geometry. The O-HÁ Á ÁO hydrogen bonding involving the water molecules located on a twofold axis links the complex molecules into a three-dimensional network.
📜 SIMILAR VOLUMES
In the cation of the title complex, [Zn(C 13 H 10 BrN 2 O)(H 2 O)]-(NO 3 )ÁH 2 O, the Zn atom is coordinated by two N and two O atoms, giving a slightly distorted square-planar geometry. The crystal structure is stabilized by intermolecular O-HÁ Á ÁO hydrogen-bond interactions.
In the mononuclear title compound, [Zn(C 13 H 15 ClNO) 2 ], the Zn II atom is four-coordinated by two N atoms and two O atoms from two Schiff base ligands in a slightly distorted tetrahedral geometry.
In the mononuclear title compound, [Zn(C 13 H 15 BrNO) 2 ], the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands.
In the mononuclear title compound, [Zn(C 13 H 15 N 2 O 3 ) 2 ], the Zn II atom is four-coordinated in a distorted tetrahedral configuration by two imine N and two phenolate O atoms from two Schiff base ligands. metal-organic papers m2496
In the title compound, [Zn(C 10 H 9 N 2 O 3 ) 2 ], the Zn II centre displays a distorted tetrahedral configuration defined by two imine N and two phenolate O atoms from two Schiff base ligands.