Chloro{2-[tris(hydroxymethyl)methyliminomethyl]phenolato}copper(II)
✍ Scribed by Ni, Jia ;Chen, Yao-Wen ;Zhang, Haidan
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 108 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
In the title compound, [Cu(C 11 H 14 NO 4 )Cl], the tridentate Schiff base ligand coordinates to the metal atom through the N and O atoms, forming a square-planar coordination geometry.
📜 SIMILAR VOLUMES
The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-
The title compound, [Cu(C 14 H 13 NO) 2 Cl 2 ], is a mononuclear copper(II) complex of a Schiff base. The Cu II atom is coordinated by two O atoms from two 2-(o-tolyliminomethyl)phenolate ligands, and by two chloride anions, forming a tetrahedral geometry.
In the mononuclear title compound, [Co(C 13 H 15 ClNO) 2 ], the Co atom is four-coordinated by two N atoms and two O atoms from two Schiff base ligands in a slightly distorted tetrahedral geometry.
In the mononuclear title compound, [Zn(C 13 H 15 ClNO) 2 ], the Zn II atom is four-coordinated by two N atoms and two O atoms from two Schiff base ligands in a slightly distorted tetrahedral geometry.