Bis{2-[(2-hydroxyethyl)iminomethyl]phenolato}gold(III) tetrachloroaurate(III)
✍ Scribed by Nockemann, Peter ;Van Hecke, Kristof ;Van Meervelt, Luc ;Binnemans, Koen
- Publisher
- International Union of Crystallography
- Year
- 2007
- Tongue
- English
- Weight
- 214 KB
- Volume
- 63
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title compound, [Co(C 14 H 12 NO 2 ) 2 ]NO 3 ÁH 2 O, is the first structurally characterized mononuclear complex of the monoanionic tridentate N-(2-hydroxymethylphenyl)salycylideneiminate ligand. The Co atom has an octahedral environment formed by two ligands with meridional coordination. metal-
In the title mononuclear cobalt(III) complex, [Co(C 11 H 14 -N 3 O 3 ) 2 ]NO 3 , the octahedral Co III atom is coordinated by two phenolate O atoms, two imine N atoms, and two amine N atoms from two Schiff base ligands. The Co III complex and the nitrate anion possess crystallographic twofold rotati
The title compound, [Co(C 16 H 21 Cl 2 N 2 O) 2 ]ClO 4 , possesses two independent half-molecules of the cation in the asymmetric unit. The symmetry of both cations is C i . The Co III atoms are six-coordinated by four N and two O atoms from two Schiff bases, forming slightly distorted octahedral co