Bis[(1,10-phenanthroline-κ2N,N′)(2-sulfidopyridine N-oxide-κ2S,O)copper(II)] tetrathionate trihydrate
✍ Scribed by Liu, Y.-F ;Xia, H.-T ;Chen, H.-W ;Wang, D.-Q
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 435 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
In the title complex, [Cu(C 7 H 3 NO 5 )(C 10 H 8 N 2 )(H 2 O)]Á3H 2 O, the Cu II atom has a slightly distorted square-pyramidal coordination geometry, with a basal plane formed by two N atoms of the 2,2 0 -bipyridine ligand and two O atoms of the pyridine-2,6-dicarboxylate N-oxide. The apical posit