Bis(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10-phenanthrolinej 2 N,N 0 0 0 )cadmium(II)-bis(l 2 -4-formylbenzoatoj 2 O:O 0 0 0 )bis[(4-formylbenzoato-j 2 O,O 0 0 0 )(1,10phenanthroline-j 2 N,N 0 0 0 )cadmium(II)] (1/1
Bis(1,10-phenanthroline-κ2N,N)bis(thiosalicylato-1κ2O,O′:2κ2O′,S)dizinc(II)
✍ Scribed by Dai, Yu-Mei ;Huang, Jin-Feng ;Shen, Hui-Ying
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 279 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.005 A Ê R factor = 0.039 wR factor = 0.087 Data-to-parameter ratio = 15.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
The title mononuclear complex, [Cu(C 2 H 3 O 3 ) 2 (C 12 H 8 N 2 )]Á-2H 2 O, is isostructural with its zinc(II) analogue. The Cu atom in the complex exists in a distorted octahedral coordination environment, defined by four O atoms and two N atoms. O-HÁ Á ÁO hydrogen bonds andstacking interactions h
In the title compound, [Cd(C 7 H 5 O 3 ) 2 (C 7 H 6 N 2 ) 2 ]ÁH 2 O, the Cd II ion is surrounded by two salicylate anions and two benzimidazole molecules in a strongly distorted octahedral cis-CdN 2 O 4 geometry. The partially overlapped arrangement and the face-to-face distances of 3.22 (3) and 3.3