𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Absolute rate constants for additions of phenylchlorocarbene to alkenes

✍ Scribed by Turro, Nicholas J.; Butcher, Jared A.; Moss, Robert A.; Guo, Wenjeng; Munjal, Ramesh C.; Fedorynski, Michal

Book ID
127346231
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
393 KB
Volume
102
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Absolute rate constants for the addition
Absolute rate constants for the additions of halophenylcarbenes to alkenes: a reactivity-selectivity relation
✍ D.Phillip Cox; Ian R. Gould; Nigel P. Hacker; Robert A. Moss; Nicholas J. Turro πŸ“‚ Article πŸ“… 1983 πŸ› Elsevier Science 🌐 French βš– 214 KB

The absolute rate constants determined for the additions of FCPh, ClCPh, and BrCPh to Me2C=CMez, MepC=CHMe, trans-MeCH=CHEt, and n-BuCH=CH2 appear to follow a reactivity/selectivity pattern of the "normal" (inverse) type.

Absolute rate constants for the addition
Absolute rate constants for the addition of hydroxymethyl radicals to alkenes in methanol solution
✍ J. Q. Wu; H. Fischer πŸ“‚ Article πŸ“… 1995 πŸ› John Wiley and Sons 🌐 English βš– 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Reaction of phenylchlorocarbene with [1.
Reaction of phenylchlorocarbene with [1.1.1] propellane: Absolute rate constants and mechanism
✍ J.C Scaiano; P.F. McGarry πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 French βš– 241 KB

Phenylchlorocarben e adds to [l.l.l] propellane with rate constants of 6.1 x 107 and 8.8 x 106 M-ts-1 in cyclohexane and acetonibile respectively to pmduce adduct V in good yields No evidence for a biradicalintem&iatewasob@ined.