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Reaction of phenylchlorocarbene with [1.1.1] propellane: Absolute rate constants and mechanism

✍ Scribed by J.C Scaiano; P.F. McGarry

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 241 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91764-7

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✦ Synopsis

Phenylchlorocarben e adds to [l.l.l] propellane with rate constants of 6.1 x 107 and 8.8 x 106 M-ts-1 in cyclohexane and acetonibile respectively to pmduce adduct V in good yields No evidence for a biradicalintem&iatewasob@ined.

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