Mechanism and rate constants for 1,3-butadiene decomposition
β Scribed by Wing Tsang; Vladmir Mokrushin
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 151 KB
- Volume
- 28
- Category
- Article
- ISSN
- 1540-7489
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π SIMILAR VOLUMES
The charaCter of rate constants for a dissociation occurring near threshold on an attractive potentialenergy surface is discussed. Application is made to the attachment of clcctrons to SF6 and CCI 4, and to the autoionization of SF;. Implications for isotope separation schemes based on the competiti
Phenylchlorocarben e adds to [l.l.l] propellane with rate constants of 6.1 x 107 and 8.8 x 106 M-ts-1 in cyclohexane and acetonibile respectively to pmduce adduct V in good yields No evidence for a biradicalintem&iatewasob@ined.
## Abstract Rate coefficients for alkyl and alkoxy radical decomposition are important in combustion, biological, and atmospheric processes. In this paper, rate constant expressions for C~1~ο£ΏC~4~ alkyl and alkoxy radicals decomposition via Ξ²βscission are recommended based on the reverse, exothermic