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Rate constants for unimolecular decomposition at threshold

✍ Scribed by Cornelius E. Klots

Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
313 KB
Volume
38
Category
Article
ISSN
0009-2614

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✦ Synopsis

The charaCter of rate constants for a dissociation occurring near threshold on an attractive potentialenergy surface is discussed. Application is made to the attachment of clcctrons to SF6 and CCI 4, and to the autoionization of SF;. Implications for isotope separation schemes based on the competition bctwcen the autoionization and dissociation of St;, are * Rcscarch sponsored by the Energy Research and Dcvclopnlcnt Administration under contract with the Union Carhide Corporation.

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