Rate and Equilibrium Constants for the Formation and Decomposition of Tetrahedral Intermediates
β Scribed by Robert A. McClelland; Linda J. Santry
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2010
- Weight
- 54 KB
- Volume
- 91
- Category
- Article
- ISSN
- 0037-9646
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π SIMILAR VOLUMES
A simple model for the energy surface of a reacting system permits the calculation of the free energies of activation. A chemical reaction is analyzed in terms of the simple processes (bond making/breaking or atom transfer; geometry changes) which must take place to achieve the overall transformatio
Rate constants have been measured at room temperature for the reactions of Cl atoms with formic acid and with the HOCO radical: Cl Ο© HCOOH !: HCl Ο© HOCO (R1) Cl Ο© HOCO !: HCl Ο© CO (R2) 2 Cl atoms were generated by flash photolysis of Cl 2 and the progress of reaction was followed by time-resolved i