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Absolute Rate Constants of Alkene Addition Reactions of a Fluorinated Radical in Water

โœ Scribed by Zhang, L.; Dolbier,, W. R.; Sheeller, B.; Ingold, K. U.


Book ID
126919840
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
57 KB
Volume
124
Category
Article
ISSN
0002-7863

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Absolute rate constants for the addition
โœ J. Q. Wu; H. Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants