✦ LIBER ✦

Absolute rate Constants for the Addition of Malonyl Radicals to Alkenes in Solution

✍ Scribed by Matthias Weber; Hanns Fischer

Publisher: John Wiley and Sons
Year: 1998
Tongue: German
Weight: 632 KB
Volume: 81
Category: Article
ISSN: 0018-019X
DOI: 10.1002/hlca.19980810327

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Absolute rate constants for the addition

Absolute rate constants for the addition of hydroxymethyl radicals to alkenes in methanol solution

✍ J. Q. Wu; H. Fischer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 753 KB

Absolute rate constants and their temperature dependencies were determined for the addition of hydroxymethyl radicals ( C H 2 0 H ) to 20 monoor 1,l-disubstituted alkenes (CH2 = C X Y ) in methanol by time-resolved electron spin resonance spectroscopy. With the alkene substituents the rate constants

Absolute Rate Constants for the Addition

Absolute Rate Constants for the Addition of Benzyl (PhĊH2) and Cumyl (PhĊMe2) Radicals to Alkenes in Solution

✍ Manfred Walbiner; Jie Qiang Wu; Hanns Fischer 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 German ⚖ 792 KB

Absolute rate constants and thzir temperature dependence were determined by time-resolved electron spin resonance for the addition of the radicals PhcH, and PhcMe, to a variety of alkenes in toluene solution. To vinyl monomers CH,=CXY, PhCH, adds at the unsubstituted C-atom with rate constants rangi

Absolute Rate Constants for the Addition

Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical to Alkenes in Solution

✍ Bernhard Knühl; Sylvain Marque; Hanns Fischer 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 German ⚖ 114 KB 👁 2 views

Absolute Rate Constants for the Addition

Absolute Rate Constants for the Addition of the 1-(tert-Butoxy)carbonylethyl Radical onto Cyclic Alkenes in Solution

✍ Hanns Fischer; Bernhard Knühl; Sylvain R. A. Marque 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 German ⚖ 46 KB 👁 1 views

## Abstract Absolute rate constants are reported for the addition of the 1‐[(__tert__‐butoxy)carbonyl]ethyl (= 2‐(1,1‐dimethylethoxy)‐1‐methyl‐2‐oxoethyl) radical ^.^CHMeCO~2~(__t‐__Bu) to several cyclic and monosubstituted alkenes in MeCN as obtained by time‐resolved electron paramagnetic resonanc

Absolute Rate Constants for the Addition

Absolute Rate Constants for the Addition of the 2-(Methoxycarbonyl)propan-2-yl and the 3,3,3-Trifluoracetonyl Radicals to Alkenes in Solution

✍ Torsten Zytowski; Bernhard Knühl; Hanns Fischer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 190 KB 👁 2 views

Rate constants for the addition of the 2

Rate constants for the addition of the 2-hydroxy-2-propyl radical to alkenes in solution

✍ K. Héberger; H. Fischer 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 432 KB 👁 1 views

Absolute rate constants for the addition of the 2-hydroxy-2-propyl radical to 18 substituted alkenes (CH2 = C X Y ) were determined at (296 -+ 1) Kin 2-propanol by time-resolved electronspin-resonance spectroscopy. With alkene substitution the rate constants vary by more than 6 orders of magnitude.