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Kinetics of cyclopropyl radical reactions. 1. Absolute rate constants for some addition and abstraction reactions

โœ Scribed by Johnston, Linda J.; Scaiano, J. C.; Ingold, K. U.


Book ID
127333939
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
617 KB
Volume
106
Category
Article
ISSN
0002-7863

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Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr

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Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M