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Rate constants for some hydrogen abstraction reactions of the carbonate radical

✍ Scribed by Carol L. Clifton; Robert E. Huie

Publisher: John Wiley and Sons
Year: 1993
Tongue: English
Weight: 243 KB
Volume: 25
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550250308

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✦ Synopsis

Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature.

Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged from 16 to 29 kJ mol-'. The results suggest that the reactions are not pure hydrogen abstraction, but involve an additional interaction of the radical with the -OH or -0 -linkage.

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