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Some hydrogen abstraction reactions of the trichloromethyl radical

✍ Scribed by Fred B. Wampler; Robert R. Kuntz

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 282 KB
Volume: 3
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550030308

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✦ Synopsis

The gas phase photolysis of CCl, in the presence of several alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the cc& radical: (4) Cc1, + RH -% CRCI, + R The following log k4 values were obtained: 2,3-Dimethylbutane C -C ~H I ~ Methy lcy clohexane log k4 10,700 f

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