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Hydrogen abstraction from trichlorosilane by the trichloromethyl and 1,1-dichlorotrifluoroethyl radicals

✍ Scribed by B. N. Ormson; W. D. Perrymore; M. L. White

Publisher: John Wiley and Sons
Year: 1977
Tongue: English
Weight: 297 KB
Volume: 9
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550090414

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✦ Synopsis

Abstract

The Arrhenius parameters for the reactions
equation image
and
equation image
have been measured. Reaction (2a) was generated and studied by the photolysis of tetrachloromethane in the presence of trichlorosilane and reaction(2b) by the photolysis of 1,1,1,‐trichlorotrifluoroethane in the presence of trichlorosilane.

The measured data are given by the expressions

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