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Some hydrogen abstraction reactions of the CF3CCl2 radical

✍ Scribed by Fred B. Wampler; Robert R. Kuntz

Publisher: John Wiley and Sons
Year: 1971
Tongue: English
Weight: 284 KB
Volume: 3
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550030602

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✦ Synopsis

The gas phase photolysis of CP3CC13 in the presence of scveral alkanes has been used to obtain Arrhenius parameters for the abstraction of hydrogen atoms by the CF3CC12 radical : CFBCCI~ + RH -+ CF3CC12H + R Activation energies of 9.6 and 8.0 kcal/mole are found for abstraction from secondary and tertiary C-H bonds, respectively. The Arrhenius parameters are compared to those for CC13 and CFI radicals.

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