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Arrhenius parameters for the reactions of trichloromethyl radicals

✍ Scribed by H. W. Sidebottom; J. M. Tedder; J. C. Walton

Publisher: John Wiley and Sons
Year: 1972
Tongue: English
Weight: 216 KB
Volume: 4
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550040212

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✦ Synopsis

The preceding paper describes the reanalysis by Kerr and Parsonage (following discussions with one of us, H.W.S.) of some of our published work. We are grateful to Dr. Kerr for communicating their conclusions to us. We agree in principle with their analysis, and the present communication is to report our acceptance of their ideas and to give a more complete recalculation of earlier work using unpublished data not available to them. T o briefly restate the problem: in a series of kinetic studies involving trichloromethyl radicals produced by the photolysis of bromotrichloromethane, we used a rate expression involving +Za 11-61:

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