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Arrhenius parameters for the decomposition of the t-butoxy radical

✍ Scribed by L. Batt; G. N. Robinson

Publisher: John Wiley and Sons
Year: 1982
Tongue: English
Weight: 146 KB
Volume: 14
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550140910

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✦ Synopsis

The recent paper of Choo and Benson [l] prompted us to communicate our most recent results for the gas-phase decomposition of the t-butoxy radical. The method we have used was to decompose ditertiary butyl peroxide (-10-5M) in the presence of nitric oxide (-10-5M) and inert gas (25-1500 torr) in a static system over the temperature range of 130-170°C. The following scheme gives the important steps in this system:

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