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Rate constants for Hydrogen abstraction reactions of NO3 in aqueous solution

✍ Scribed by L. V. Shastri; Robert E. Huie

Publisher: John Wiley and Sons
Year: 1990
Tongue: English
Weight: 392 KB
Volume: 22
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550220507

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✦ Synopsis

Rate constants have been measured by pulse radiolysis for the reactions of the NO, radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 x lo4 M-' 5 -l for deuterated methanol to 1.1 x lo7 M-' 5-l for tetrahydrofuran. The rate constants for the reactions of NO3 with the alcohols 1-propanol to 1-heptanol were found to be linearly dependent on the number of CH2 groups with a group reactivity of 6.4 x lo5 M-' s-'.

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