dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac
โฆ LIBER โฆ
Rate Constants for Reactions of Phenoxyl Radicals in Solution
โ Scribed by Pedatsur Neta; Jan Grodkowski
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 8 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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Rate constants have been measured at room temperature for the reactions of Cl atoms with formic acid and with the HOCO radical: Cl ฯฉ HCOOH !: HCl ฯฉ HOCO (R1) Cl ฯฉ HOCO !: HCl ฯฉ CO (R2) 2 Cl atoms were generated by flash photolysis of Cl 2 and the progress of reaction was followed by time-resolved i