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ChemInform Abstract: Aqueous Solution Reaction Rate Constants for Hydrogen Atoms

✍ Scribed by Keith P. Madden; Stephen P. Mezyk

Publisher: John Wiley and Sons
Year: 2011
Weight: 18 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201147264

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📜 SIMILAR VOLUMES

Rate constants for Hydrogen abstraction

Rate constants for Hydrogen abstraction reactions of NO3 in aqueous solution

✍ L. V. Shastri; Robert E. Huie 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 392 KB 👁 2 views

Rate constants have been measured by pulse radiolysis for the reactions of the NO, radical with five cyclic ethers and a series of alcohols. Rate constants ranged from 3.5 x lo4 M-' 5 -l for deuterated methanol to 1.1 x lo7 M-' 5-l for tetrahydrofuran. The rate constants for the reactions of NO3 wit

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Laser flash photolysis (at 248 or 308 nm) or aryl iodides in water or water/methanol solutions produces iodine atoms and phenyl radicals. Iodine atoms react rapidly with added I-to form 12-but do not react rapidly with 0 2 ( k I lo7 L mol-l s-l). Iodine atoms oxidize phenols to phenoxyl radicals, wi

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Rate constants for some reactions of free radicals with haloacetates in aqueous solution

✍ Pichai Maruthamuthu; S. Padmaja; Robert E. Huie 📂 Article 📅 1995 🏛 John Wiley and Sons 🌐 English ⚖ 443 KB 👁 1 views

The kinetics of the acqueous-phase reactions of the free radicals .OH, .Cl,, and SO; . with the halogenated acetates, CHzFCOO-, CHF2COO-, CF3COO-, and with CHzClC00-, CHClzC00-, CC13COOwere investigated. Generally, the reactivity decreases with increasing halogen substitution and is in the order k(.

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Rate constants for the OH reactions with oxygenated organic compounds in aqueous solution

✍ S. Gligorovski; D. Rousse; C. H. George; H. Herrmann 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 344 KB 👁 1 views

## Abstract The kinetics of the oxidation of functionalized organic compounds of atmospheric relevance by the hydroxyl radical (OH) was measured in the aqueous phase. Competition kinetics, using the thiocyanate anion (SCN^−^) as competitor, was applied using both a laser flash photolysis long path

Rate constants for some hydrogen abstrac

Rate constants for some hydrogen abstraction reactions of the carbonate radical

✍ Carol L. Clifton; Robert E. Huie 📂 Article 📅 1993 🏛 John Wiley and Sons 🌐 English ⚖ 243 KB 👁 1 views

Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr

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Temperature dependence of rate constants for the reaction of atomic oxygen with hydrogen chloride

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## Abstract A phase‐shift method has been used to determine the rate constant for the reaction of ground state oxygen atoms with HCl over the temperature range of 330–600 K. Oxygen atoms were generated by modulated mercury photosensitized decomposition of N~2~O, and monitored by the chemiluminescen