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Rate constants for ring openings of 2-phenylcyclobutylcarbinyl radicals

โœ Scribed by Calvin J. Emanuel; John H. Horner; Martin Newcomb


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
65 KB
Volume
13
Category
Article
ISSN
0894-3230

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dicted rate constants are invariably dominated by a 'Reaction with N'). While AOP treats amides as amines, we expect amides to be less reactive than amines from the analogous relationship between esters and ethers (see [3] for OH rate constants): if amines are matched to ethers (both are highly reac

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The rate constants for the reactions of OH radicals with CH 3 OCF 2 CF 3 , CH 3 OCF 2 CF 2 CF 3 , and CH 3 OCF(CF 3 ) 2 have been measured over the temperature range 250-430 K. Kinetic measurements have been carried out using the flash photolysis, laser photolysis, and discharge flow methods combine

Rate constants for the reaction of OH ra
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Rate constants of OH radical reaction with some amino polycarboxylic acids (APCAs) such as EDTA, DTPA, HEDTA, NTA, and HIDA have been determined at different pHs using pulse radiolysis competition kinetics method with thiocyanate as the reference solute. The rate constants varied with pH (possibly d

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Rate constants have been measured at room temperature for the reactions of Cl atoms with formic acid and with the HOCO radical: Cl ฯฉ HCOOH !: HCl ฯฉ HOCO (R1) Cl ฯฉ HOCO !: HCl ฯฉ CO (R2) 2 Cl atoms were generated by flash photolysis of Cl 2 and the progress of reaction was followed by time-resolved i