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Reactions of alkoxy radicals. IV. Kinetics and absolute rate constants for some tert-butyl hypochlorite chlorinations

โœ Scribed by Carlsson, D. J.; Ingold, Keith U.


Book ID
121505559
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
478 KB
Volume
89
Category
Article
ISSN
0002-7863

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Nucleophilic character of the tert-butyl
โœ H. R. Dรผtsch; H. Fischer ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 254 KB ๐Ÿ‘ 1 views

## Abstract The decay of photochemically generated __tert__โ€butyl radicals is studied at 48ยฐC in 11 __m__โ€ and __p__โ€substituted toluenes by timeโ€resolved electron spin resonance spectroscopy. It is governed by the secondโ€order selfโ€termination perturbed by a pseudoโ€firstโ€order reaction of the radi