## Abstract The rate constant for __tert__‐butyl radical recombination has been measured near 700°K by the very‐low‐pressure pyrolysis (VLPP) technique and was found to be 10^8.8±0.3^ __M__^−1^·sec^−1^ with neglibible temperature dependence. The thermochemical parameters for __tert__butyl radicals
Absolute Rate Constants for the Combination of Trichloromethyl Radicals and for Their Reaction with t-Butyl Hypochlorite 1
✍ Scribed by Carlsson, D. J.; Howard, J. A.; Ingold, K. U.
- Book ID
- 127130073
- Publisher
- American Chemical Society
- Year
- 1966
- Tongue
- English
- Weight
- 147 KB
- Volume
- 88
- Category
- Article
- ISSN
- 0002-7863
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📜 SIMILAR VOLUMES
## Abstract The rate constant for the bimolecular combination of trichloromethyl radicals in methanol is determined as a function of temperature by steady‐state kinetics and electron‐spin resonance with modulated radical initiation. The rate constant is in accord with the Smoluchowski equation and
## Abstract The decay of photochemically generated __tert__‐butyl radicals is studied at 48°C in 11 __m__‐ and __p__‐substituted toluenes by time‐resolved electron spin resonance spectroscopy. It is governed by the second‐order self‐termination perturbed by a pseudo‐first‐order reaction of the radi