๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Pentamethyldisilyl radical: absolute rate constants for its formation and for some halogen abstraction and addition reactions

โœ Scribed by Lusztyk, J.; Maillard, B.; Ingold, K. U.

Book ID
127361598
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
519 KB
Volume
51
Category
Article
ISSN
0022-3263

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Rate constants for some hydrogen abstrac
Rate constants for some hydrogen abstraction reactions of the carbonate radical
โœ Carol L. Clifton; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1993 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 243 KB ๐Ÿ‘ 1 views

Rate constants have been measured in aqueous solutions for the reactions of the carbonate radical, COs'-, with several saturated alcohols and one cyclic ether as a function of temperature. Arrhenius pre-exponential factors ranged from 2 X lo8 to 1 X lo9 e mol-' s-l and activation energies ranged fr

Absolute rate constants for hydrogen abs
Absolute rate constants for hydrogen abstraction from hydrocarbons by the trichloromethylperoxyl radical
โœ S. Mosseri; Z. B. Alfassi; P. Neta ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 357 KB

Absolute rate constants have been measured for the reactions of trichloromethylperoxyl radicals with cyclohexane, cyclohexene, and hexamethylbenzene. The CClsO, radicals were produced by pulse radiolysis of air-saturated CCl, solutions containing various amounts of the hydrocarbons. The rate constan

Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4โˆ’. Alcohols
โœ Carol L. Clifton; Robert E. Huie ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 504 KB

Rate constants have been determined for the reactions of SO4with a series of alcohols, including hydrated formaldehyde. The SO,radical was produced by the laserflash photolysis of persulfate, Sz02-. Rate constants for the reactions of SO4with alcohols range from 1.0 x lo7 for methanol to 3.4 x 10' M

Rate constants for hydrogen abstraction
Rate constants for hydrogen abstraction reactions of the sulfate radical, SO4โˆ’. Alkanes and ethers
โœ Robert E. Huie; Carol L. Clifton ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 451 KB ๐Ÿ‘ 1 views

Rate constants have been determined for the reactions of SO4with a series of alkanes and ethers. The SO, radical was produced by the laser-flash photolysis of persulfate, SZO: -. For methane, only an upper limit of 1 x lo6 M-' s-\* could be determined. For ethane, propane, and 2-methylpropane, rate